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Electronic spectra of ArXe molecules in the region of Xe* (6s', 6p, 5d), 77 000–80 200 cm−1, using resonantly enhanced multiphoton ionization

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Published 7 July 2010 2010 IOP Publishing Ltd
, , Citation M A Khodorkovskii et al 2010 J. Phys. B: At. Mol. Opt. Phys. 43 155101 DOI 10.1088/0953-4075/43/15/155101

0953-4075/43/15/155101

Abstract

The excited electronic states of ArXe molecules in the region 77 000–80 200 cm−1 were studied using the (2+1) and (3+1) resonance-enhanced multiphoton ionization methods. The use of different methods of multi-photon excitation and Ar+ ion registration allowed us to obtain some new data. Molecular constants were obtained for previously unknown excited states of molecules with the following dissociation limits: ArXe* → Ar1S0+Xe*6р[5/2]3 with Ω = 2, 3 symmetry; Ar1S0+Xe*6p[3/2]2 with Ω = 1, 2 symmetry; Xe0S1 → Xe*6s'[1/2]01 with Ω = 0+ symmetry.

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10.1088/0953-4075/43/15/155101