A E Kingston and A Hibbert 2009 J. Phys. B: At. Mol. Opt. Phys. 42 185004 doi:10.1088/0953-4075/42/18/185004
A E Kingston and A Hibbert
Show affiliationsTheoretical calculations were previously undertaken, using the computer code CIV3, to calculate transition energies, oscillator strengths and A-values for transition from the 3p63d ground state to the doublet excited states of Ti IV (Kingston A E and Hibbert A 2006 J. Phys. B: At. Mol. Opt. Phys. 39 2217–30). In this paper, these calculations are extended to include both doublet and quartet excited states and to permit mixing between them. Transition energies, oscillator strengths and A-values are obtained for transitions from the 3p63d 2D ground state of Ti IV to the 3p6np 2P° (n = 4 to 10), 3p6nf 2F° (n = 4 to 10) excited states and also to the excited states 2S°, 2P°, 2D°, 2F°, 4S°, 4P°, 4D°, 4F° and 4G° given by 3p53d4s and 3p53d2 configurations. The transition energies are compared with the transition energies measured using vacuum sparks (Ryabtsev et al 2005 Opt. Spectrosc. 98 519–27). The A-values are compared with the semiempirical calculations of Ryabtsev et al and the measurements of Schippers et al (2004 J. Phys. B: At. Mol. Opt. Phys. 37 L209–16). The calculations are also compared with the most recent theoretical calculations of transition energies and A-values of Ti IV given by Nikolic et al (2009 Phys. Rev. A 79 012703).
32.70.Cs Oscillator strengths, lifetimes, transition moments
32.80.Fb Photoionization of atoms and ions
31.15.-p Calculations and mathematical techniques in atomic and molecular physics
Issue 18 (28 September 2009)
Received 22 June 2009, in final form 22 July 2009
Published 9 September 2009
A E Kingston and A Hibbert 2009 J. Phys. B: At. Mol. Opt. Phys. 42 185004
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