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Transitions from the ground state of Ti IV to excited doublet and quartet states

A E Kingston and A Hibbert

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Theoretical calculations were previously undertaken, using the computer code CIV3, to calculate transition energies, oscillator strengths and A-values for transition from the 3p63d ground state to the doublet excited states of Ti IV (Kingston A E and Hibbert A 2006 J. Phys. B: At. Mol. Opt. Phys. 39 2217–30). In this paper, these calculations are extended to include both doublet and quartet excited states and to permit mixing between them. Transition energies, oscillator strengths and A-values are obtained for transitions from the 3p63d 2D ground state of Ti IV to the 3p6np 2P° (n = 4 to 10), 3p6nf 2F° (n = 4 to 10) excited states and also to the excited states 2S°, 2P°, 2D°, 2F°, 4S°, 4P°, 4D°, 4F° and 4G° given by 3p53d4s and 3p53d2 configurations. The transition energies are compared with the transition energies measured using vacuum sparks (Ryabtsev et al 2005 Opt. Spectrosc. 98 519–27). The A-values are compared with the semiempirical calculations of Ryabtsev et al and the measurements of Schippers et al (2004 J. Phys. B: At. Mol. Opt. Phys. 37 L209–16). The calculations are also compared with the most recent theoretical calculations of transition energies and A-values of Ti IV given by Nikolic et al (2009 Phys. Rev. A 79 012703).


PACS

32.70.Cs Oscillator strengths, lifetimes, transition moments

32.80.Fb Photoionization of atoms and ions

31.15.-p Calculations and mathematical techniques in atomic and molecular physics

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 18 (28 September 2009)

Received 22 June 2009, in final form 22 July 2009

Published 9 September 2009



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