On some aspects of changing the sign of the dipole moment functions of diatomic molecules

doi:10.1088/0953-4075/42/10/105102

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Journal of Physics B: Atomic, Molecular and Optical Physics

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Journal of Physics B: Atomic, Molecular and Optical Physics Volume 42 Number 10 Create an alert RSS this journal

M A Buldakov et al 2009 J. Phys. B: At. Mol. Opt. Phys. 42 105102 doi:10.1088/0953-4075/42/10/105102

On some aspects of changing the sign of the dipole moment functions of diatomic molecules

M A Buldakov¹, V N Cherepanov², E V Koryukina² and Yu N Kalugina²

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Abstract References Cited By

Ab initio calculations of asymptotic dipole moment functions of some diatomic molecules at R → 0 have been carried out. It was achieved that in a range of small internuclear separations, the dipole moment functions of the molecules CO, NO, BF and BeNe for ground electronic states have an additional change of the sign.

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Journal of Physics B: Atomic, Molecular and Optical Physics

On some aspects of changing the sign of the dipole moment functions of diatomic molecules

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