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Coherent control of electron wave packets in dissociating H+2

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Feng He1, Camilo Ruiz2 and Andreas Becker

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Coherent control of electron localization in the dissociation of a hydrogen molecular ion exposed to an attosecond pulse train and a time-delayed near-infrared laser pulse are studied by solving numerically the time-dependent Schrödinger equation. The attosecond pulses in the train generate a train of electron wave packets in the dissociating molecular ion, which are steered by the near-infrared laser field between the two nuclei. Our results show that a large asymmetry in the total electron localization can be achieved if the attosecond pulses are separated by a full cycle of the near-infrared pulse, while the asymmetry and the degree of control are much smaller for a pulse separation of half a cycle. The analysis of results reveals an efficient control mechanism on a timescale of few femtoseconds via the time-delay and the carrier-to-envelope phase of the near-infrared pulse.


PACS

33.80.Gj Diffuse spectra; predissociation, photodissociation

42.65.Re Ultrafast processes; optical pulse generation and pulse compression

42.50.-p Quantum optics

Subjects

Atomic and molecular physics

Optics, quantum optics and lasers

Dates

Issue 8 (28 April 2008)

Received 8 January 2008

Published 3 April 2008



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