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On the importance of inner-shell contributions to multiphoton ionization of complex atoms in the VUV regime

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Linda Hamonou and Hugo W van der Hart

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Using the R-matrix-Floquet approach, we investigate two-photon ionization of the Ne+1s22s22p5 ground state irradiated by laser light with photon energies between 25 and 40 eV. We find that the ionization rates can increase by over an order of magnitude if, in addition to emission of a 2p electron, we also include emission of a 2s electron, and we use target states based on a considerable configuration-interaction expansion. The improved agreement with experiment demonstrates that the inclusion of inner-shell excitation and ionization processes is essential for theory to accurately describe the experimental multiphoton ionization cross sections in the VUV regime.


PACS

32.80.Rm Multiphoton ionization and excitation to highly excited states

32.80.Hd Auger effect (including Coster-Krönig transitions)

31.15.ve Electron correlation calculations for atoms and ions: ground state

31.15.xr Self-consistent-field methods

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 12 (28 June 2008)

Received 30 April 2008, in final form 15 May 2008

Published 6 June 2008



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