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Collisional broadening of alkali doublets by helium perturbers

D F T Mullamphy1, G Peach2, V Venturi1,3, I B Whittingham1 and S J Gibson1

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We report results for the Lorentzian profiles of the Li I, Na I and K I doublets and the Na I subordinate doublet broadened by helium perturbers for temperatures up to 3000 K. They have been obtained from a fully quantum-mechanical close-coupling description of the colliding atoms, the Baranger theory of line shapes and new ab initio potentials for the alkali–helium interaction. For all lines except the 769.9 nm K I line, the temperature dependence of the widths over the range 70 ≤ T ≤ 3000 K is accurately represented by the power law form w = aTbb with 0.38 < b < 0.43. The 769.9 nm K I line has this form for 500 ≤ T ≤ 3000 K with b having the higher value of 0.49. Although the shifts have a more complex temperature dependence, they all have the general feature of increasing with temperature above T ~ 500 K apart from the 769.9 K I line whose shift decreases with temperature.


PACS

34.20.Cf Interatomic potentials and forces

95.30.Ky Atomic and molecular data, spectra, and spectral parameters (opacities, rotation constants, line identification, oscillator strengths, gf values, transition probabilities, etc.)

32.70.Jz Line shapes, widths, and shifts

97.20.Vs Low luminosity stars, subdwarfs, and brown dwarfs

Subjects

Atomic and molecular physics

Astrophysics and astroparticles

Dates

Issue 6 (28 March 2007)

Received 29 September 2006, in final form 18 December 2006

Published 5 March 2007



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