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Oscillatory differential cross sections for Li + He, Ne, H2 and D2 optical collisions

A Grimpe1, C Figl1, J Grosser1, O Hoffmann1 and F Rebentrost2

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We report measurements of differential cross sections for optical collisions of Li atoms with He and Ne atoms and H2 and D2 molecules. Oscillatory structures are observed in all cases. For the atomic targets, we find a very good agreement with theoretical results based on close-coupling scattering calculations and recent quantum chemical data, and we derive estimates for the accuracy of the calculated potentials. For the molecular targets, calculations using the rotational sudden approach yield a good agreement with the experiment.


PACS

34.35.+a Interactions of atoms and molecules with surfaces

34.10.+x General theories and models of atomic and molecular collisions and interactions (including statistical theories, transition state, stochastic and trajectory models, etc.)

Subjects

Atomic and molecular physics

Dates

Issue 1 (14 January 2005)

Received 8 October 2004, in final form 17 November 2004

Published 20 December 2004



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