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One- and two-photon picosecond excitation dynamics of the singlet states of a tetraphenyl-diamine derivative in solution

Barbara Paci1,3, Chantal Andraud2, Remi Anemian2,4 and Jean-Michel Nunzi1,5

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We report on nonlinear absorption measurements of a tetraphenyl-diamine dye which was developed to be used as a transparent two-photon-type molecular material for optical limiting applications in the visible range. The excited state properties which are relevant to the process are investigated experimentally using picosecond nonlinear optical Kerr ellipsometry for differential absorption cross section monitoring. Results of the picosecond one- and two-photon absorption dynamics are presented. Time-resolved excited state absorption properties are discussed in terms of the optical limiting application.


PACS

42.70.Nq Other nonlinear optical materials; photorefractive and semiconductor materials

42.50.Md Optical transient phenomena: quantum beats, photon echo, free-induction decay, dephasings and revivals, optical nutation, and self-induced transparency

42.65.Hw Phase conjugation; photorefractive and Kerr effects

78.47.-p Spectroscopy of solid state dynamics

42.70.Jk Polymers and organics

33.80.Rv Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states)

Subjects

Atomic and molecular physics

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Optics, quantum optics and lasers

Dates

Issue 8 (28 April 2004)

Received 8 August 2003

Published 1 April 2004



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