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Multiplet-specific N 1s photoelectron angular distributions from the fixed-in-space NO molecules

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K Hosaka1, J Adachi1,2, M Takahashi3, A Yagishita1,2, P Lin4 and R R Lucchese4

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LETTER TO THE EDITOR

Angular distributions of multiplet-specific N 1s photoelectrons from the fixed-in-space NO molecules have been measured for the first time. The dynamics of the σ* shape resonance appearing in the channel leading to the 3Π and 1Π ionic states has been made clear from the analyses of the angular distributions. Multiplet-specific multichannel calculations have reproduced the observed angular distributions fairly well.


PACS

33.80.Eh Autoionization, photoionization, and photodetachment

33.60.+q Photoelectron spectra

34.50.Lf Chemical reactions

Subjects

Atomic and molecular physics

Dates

Issue 3 (14 February 2004)

Received 7 November 2003

Published 20 January 2004



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