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Repulsive KAr potentials from differential optical collisions

C Figl1, J Grosser1, O Hoffmann1 and F Rebentrost2

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Experimental differential cross sections for the optical collision process K(4s)2S + Ar + hν → K(4p)2P + Ar are reported. The characteristic interference structures are used to determine the repulsive parts of the KAr X2Σ and B2Σ potential curves by comparison with the results of exact quantum coupled-channel scattering calculations. By a least-squares procedure we obtain potentials with a relative accuracy of typically 1% in the range 0 ≤ V ≤ 1000–1500 cm−1, corresponding to absolute values of 2–4 cm−1 for the larger and 10–15 cm−1 for the smaller distances sampled by the experiment.


PACS

32.80.-t Photoionization and excitation

34.20.-b Interatomic and intermolecular potentials and forces, potential energy surfaces for collisions

31.15.-p Calculations and mathematical techniques in atomic and molecular physics

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 16 (28 August 2004)

Received 7 May 2004

Published 9 August 2004



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