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Coupled channel representation of the advanced adiabatic approach

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P S Krstić

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LETTER TO THE EDITOR

A treatment of the heavy particle collision dynamics in a form of molecular orbital coupled channel approach, emerging from the hidden crossings topology of the complex adiabatic eigenenergy surface, is proposed. We show how this can be self-consistently adjusted for application in the nearly adiabatic limit of collision energies. The method is tested for the charge transfer process in He2++H collisions, in a range of 10–400 eV/u collision energies. Excellent agreement of the partial and total cross sections with other accurate theories and experiments is shown, and comparative advantages of the method are discussed.


PACS

31.15.bw Coupled-cluster theory

34.70.+e Charge transfer

32.70.Cs Oscillator strengths, lifetimes, transition moments

34.50.-s Scattering of atoms and molecules

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 11 (14 June 2004)

Received 23 February 2004

Published 17 May 2004



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