Quick search Find article
Quick search
Find article

Nonadiabatic molecular response to short, intense laser pulses: a wave operator generalized Floquet approach

G Jolicard1, O Atabek2, M L Dubernet-Tuckey3 and N Balakrishnan4

Show affiliations


A generalized Floquet formalism combined with Bloch's wave operator methodology is applied to the study of adiabatic versus sudden transport mechanisms in molecular responses to ultrashort and intense laser pulses. The model considers the laser pulse as a whole to be periodic, instead of the optical cycle as in standard Floquet treatments. This leads to a better understanding of the dynamics and a considerable simplification in terms of the number of generalized Floquet eigenstates needed to accurately describe the dynamics. The method is illustrated for the phenomenon of above threshold dissociation and inelastic transitions in H2+ in the presence of ultrashort (a few femtoseconds) and intense (of the order of TW cm−2) laser fields. It is found that, while the dissociation probabilities and fragment kinetic energy spectra can be accurately described by a single generalized Floquet eigenstate within the adiabatic limit, an accurate description of inelastic transitions requires more than one generalized Floquet state, due to the role of non-adiabatic dynamics.


PACS

42.65.Re Ultrafast processes; optical pulse generation and pulse compression

33.80.Gj Diffuse spectra; predissociation, photodissociation

42.60.Fc Modulation, tuning, and mode locking

33.70.Ca Oscillator and band strengths, lifetimes, transition moments, and Franck-Condon factors

Subjects

Atomic and molecular physics

Optics, quantum optics and lasers

Dates

Issue 13 (14 July 2003)

Received 13 January 2003

Published 19 June 2003



  1. Nonadiabatic molecular response to short, intense laser pulses: a wave operator generalized Floquet approach

    G Jolicard et al 2003 J. Phys. B: At. Mol. Opt. Phys. 36 2777

  2. An introduction to the covariant quantization of superstrings

    P A Grassi et al 2003 Class. Quantum Grav. 20 S395

  3. Zeno dynamics in quantum statistical mechanics

    Andreas U Schmidt 2003 J. Phys. A: Math. Gen. 36 1135

  4. Conduction band electronic structure of metallic beryllium

    V A Sashin et al 2001 J. Phys.: Condens. Matter 13 4203

  5. Spectral momentum densities of vanadium and vanadium oxide as measured by high energy (e, 2e) spectroscopy

    C Chen et al 2005 J. Phys.: Condens. Matter 17 7689

  6. Generating function techniques for loop quantum cosmology

    Daniel Cartin et al 2004 Class. Quantum Grav. 21 4495

  7. DWBA-G calculations of electron impact ionization of noble gas atoms

    A S Kheifets et al 2008 J. Phys. B: At. Mol. Opt. Phys. 41 145201

  8. High harmonics generation from excited states of atomic lithium

    I A Ivanov and A S Kheifets 2008 J. Phys. B: At. Mol. Opt. Phys. 41 115603

  9. D-branes at singularities, compactification, and hypercharge

    Matthew Buican et al JHEP01(2007)107

  10. A-Model correlators from the Coulomb branch

    Ilarion V. Melnikov and M. Ronen Plesser JHEP02(2006)044

View by subject




Export








Please login to access our web services, or create an account if you don't yet have one.

You must have cookies enabled in your web browser to be able to login.

Username
Password

Forgotten your password? Get a new one here.