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Linear dichroism in the 4d photoionization of atomic europium

J Schulz1,4, Ph Wernet1,5, K Godehusen2, R Müller2, P Zimmermann2, M Martins3 and B Sonntag1

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The dichroism in the 4d photoelectron spectra of laser polarized Eu atoms has been determined with linearly polarized soft x-ray radiation. The results are discussed in comparison with the predictions by the LS-coupling model and by configuration interaction Hartree-Fock calculations, thereby demonstrating the strong influence of valence electron correlations. The interpretation of the dichroism in the 4d photoelectron spectra of solid Gd in terms of an ionic model is corroborated by the close similarity of the Gd solid and the Eu atom spectra.


PACS

32.80.Fb Photoionization of atoms and ions

31.15.xr Self-consistent-field methods

31.15.V- Electron correlation calculations for atoms, ions and molecules

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 4 (28 February 2002)

Received 4 September 2001, in final form 29 November 2001

Published 13 February 2002



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