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Observation and interpretation of the metastable 3p63d Ca+ ion spectrum in the 3p excitation region

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H Kjeldsen1, F Folkmann1, F Innocenti2, L Zuin2 and J E Hansen3

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LETTER TO THE EDITOR

A measurement of the 3p absolute photoionization cross section of Ca+ ions is reported. The experiments were performed by means of the merged-beam technique and utilizing a target ion beam containing both 3p64s ground-state ions and 3p63d metastable ions. By combining measurements performed with different fractions of metastable ions, it was possible to obtain separate cross-section data for the two species, and we present here for the first time the photoionization spectrum of the metastable 3p63d state of the Ca+ ion. Comparison with theoretical predictions allows an interpretation of the strongest features in terms of 3p → 3d transitions.


PACS

32.80.Fb Photoionization of atoms and ions

31.15.vj Electron correlation calculations for atoms and ions: excited states

34.50.-s Scattering of atoms and molecules

31.15.ve Electron correlation calculations for atoms and ions: ground state

32.80.Rm Multiphoton ionization and excitation to highly excited states

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 15 (14 August 2002)

Received 12 June 2002

Published 29 July 2002



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