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Theory and practice in low-energy electron excitation of the levels of xenon

S Nakazaki-+, K A Berrington++, W B Eissner§ and Y Itikawa||

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LETTER TO THE EDITOR

This letter concerns low-energy electron excitation from the ground state of xenon to the lowest four excited levels ( and ). We report here on the first results from Breit - Pauli R-matrix theory which investigates coupling to the 6 p and 5 d levels: specifically, in 5-, 15- and 22-level calculations. Differential cross sections at 15 eV are compared with other theories and with experiments. Our present 22-level R-matrix calculation represents the most elaborate on this system to date and gives reasonable agreement with experiments, though some discrepancies remain. We note that perturbative approaches such as recent distorted-wave calculations agree less well with experiments, and we conclude from this and from other evidence that such methods, as currently formulated, are not reliable for describing low-energy scattering from neutral systems. On the other hand, the R-matrix method appears to be capable of systematic improvement via the introduction of further states and pseudostates.


PACS

34.80.Dp Atomic excitation and ionization

31.15.xp Perturbation theory

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 2 (28 January 1997)

Received 21 October 1996



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