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Accurate analytic wavefunctions for two-electron atoms

C Le Sech

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LETTER TO THE EDITOR

Simple analytic two variational parameters wavefunctions for the ground state of , He, , , atom (ions) are proposed. These functions fulfil the cusp conditions at the singularities of the Coulombic field, and include the correct behaviour for large interparticle separations. The accuracy of the calculated energies is found to be about . These functions should be useful for the computation of the cross section of inelastic processes involving two-electron systems.


PACS

34.10.+x General theories and models of atomic and molecular collisions and interactions (including statistical theories, transition state, stochastic and trajectory models, etc.)

Subjects

Atomic and molecular physics

Dates

Issue 2 (28 January 1997)

Received 16 October 1996



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