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Photoabsorption study of ligand-field splitting of Br-3d levels in HBr

R Puttner, M Domke, K Schulz, A Gutierrez and G Kaindl

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The inner-shell photoabsorption spectrum of gas-phase HBr below the Br-3d ionization thresholds was measured with high spectral resolution. Ligand-field splitting of the Br-3d levels could be clearly resolved in photoabsorption, in agreement with observations made in recent photoemission work. The good signal-to-noise ratio of the present photoabsorption spectrum allowed to follow the ligand-field splitting of 3d-core-excited np Rydberg states up to high quantum numbers (n=9), and to assign some additional weak transitions that could not be resolved before.


PACS

33.20.-t Molecular spectra

33.70.Ca Oscillator and band strengths, lifetimes, transition moments, and Franck-Condon factors

Subjects

Atomic and molecular physics

Dates

Issue 12 (28 June 1995)



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