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Mollow splitting of the Na D fluorescence lines in an Ar-filled vapour cell

A R D van Bergen, H J van Halewijn, T Hollander and C T J Alkemade

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The authors have measured time-resolved fluorescence spectra of the Na D lines in an Ar-filled vapour cell, excited by a high-intensity, pulsed dye laser of narrow bandwidth, which was tuned near the D1 line. The results were compared with a recent theory which also takes into account the polarisation of the laser and the Zeeman degeneracy of the atomic levels. In particular, they predicted and observed a splitting into two components of the D2 line (whose upper level is populated by mixing collisions), which is a new effect. Because of experimental difficulties, however, they obtained at most a semiquantitative agreement between theory and experiment.


PACS

32.50.+d Fluorescence, phosphorescence (including quenching)

32.70.-n Intensities and shapes of atomic spectral lines

32.80.-t Photoionization and excitation

Subjects

Atomic and molecular physics

Dates

Issue 4 (28 February 1988)



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