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Mode of lead addition and its effects on phase formation and microstructure development in composite conductors

J S Luo-+, S E Dorris-+, A K Fischer-+, J S LeBoy-+, V A Maroni-+, Y Feng++ and D C Larbalestier++

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An extensive examination has been made of silver-sheathed (Bi-2223) composite conductors produced by the two-powder processing method, wherein single-phase (Bi-2212) is combined with a mix of Pb-Ca-Cu-O phases to give an overall stoichiometry of . The principal variable is the proportioning of lead between the Bi-2212 phase and the Pb-Ca-Cu-O phases. X-ray diffraction measurements and scanning electron microscopy analyses have revealed that the length of the induction period prior to the onset of Bi-2223 formation decreases monotonically as the initial lead fraction in the Bi-2212 is increased up to a value of 0.3. The observed decrease in critical current density of fully processed composites with decreasing lead fraction in the Bi-2212 phase appears to be more closely related to the quantity of unconverted Bi-2212 than to the quantity of residual alkaline earth cuprate secondary phases. Transmission electron microscopy shows that the frequency of Bi-2212 intergrowths declines with increasing lead fraction in the starting Bi-2212 component.


PACS

74.81.Bd Granular, melt-textured, amorphous and composite superconductors

74.72.Hs Bi-based cuprates

74.25.Sv Critical currents

68.37.Lp Transmission electron microscopy (TEM)

Subjects

Superconductivity

Surfaces, interfaces and thin films

Dates

Issue 5 (May 1996)

Received 15 January 1996



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