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Rietveld analysis and superconductivity of compounds

H-C I Kao-+, Y D Leu-+, W N Huang-+, C-M Wang-+, D H Chen++ and T J Lee§

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A series of single-phase compounds with tetragonal triple-perovskite structure is studied by Rietveld analysis. For , all of the ions enter the centre site: the site of the tetragonal phase. For , a maximum of about 1/2 of the sites are occupied by ions and the extra ions enter the site. Double plateaux are found between and (the difference between the occupancy factor of ions at the site and that of ions at the site). It is suggested that of the La - Ca - Ba - Cu - O compounds containing 50 mol% copper atoms with tetragonal triple-perovskite structure can be predicted from the correlation of versus .


PACS

74.72.Dn La-based cuprates

74.62.-c Transition temperature variations

61.05.cp X-ray diffraction

Subjects

Superconductivity

Dates

Issue 10 (October 1996)

Received 1 July 1996



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