H-C I Kao et al 1996 Supercond. Sci. Technol. 9 893 doi:10.1088/0953-2048/9/10/011
compounds
H-C I Kao
, Y D Leu
, W N Huang
, C-M Wang
, D H Chen
and T J Lee§
A series of single-phase
compounds with tetragonal triple-perovskite structure is studied by Rietveld analysis. For
, all of the
ions enter the centre site: the
site of the tetragonal
phase. For
, a maximum of about 1/2 of the
sites are occupied by
ions and the extra
ions enter the
site. Double plateaux are found between
and
(the difference between the occupancy factor of
ions at the
site and that of
ions at the
site). It is suggested that
of the La - Ca - Ba - Cu - O compounds containing 50 mol% copper atoms with tetragonal triple-perovskite structure can be predicted from the correlation of
versus
.
Issue 10 (October 1996)
Received 1 July 1996
compounds
H-C I Kao et al 1996 Supercond. Sci. Technol. 9 893
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