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The influence of fluoride ions on the properties of (Tl, Pb) 1223 superconductors

Manfred Enengl and Gerhard Gritzner

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(Tl0.5Pb0.5)(Sr(0.75–0.9)Ba(0.1–0.25))2Ca2Cu3OxFy bulk superconductors have been prepared by partial replacement of CaO by CaF2 and of BaO by BaF2 in the starting materials via the mixed oxide method. The addition of either CaF2 or BaF2 as a fluoride ion source yielded predominantly the SrF2 secondary phase. The critical temperatures decreased by 5 to 20 K compared to the critical temperature of the samples prepared without the addition of CaF2 or BaF2. Annealing at 820 °C yielded comparable Tc(0) values between 114 and 119 K for both the fluoride containing and fluoride-free samples. The critical current densities at 77 K decreased. Partial or complete substitution of Tl2O3 by TlF in the starting material led to critical temperatures (Tc(0)) between 115 and 117 K and the formation of large grains (up to 200 µm). The concentration of fluoride ions in the superconducting crystallites was below the detection limit of the energy dispersive x-ray fluorescence analysis. Excellent results were obtained when TlF was used in thallium sources for in situ preparation of screen-printed thick films on single-crystal LaAlO3. The x-ray diffraction pattern showed that very well textured Tl-1223 crystallites were formed. The critical temperature Tc(0) for these films was about 117 K with transition widths (ΔTc(90–10%)) smaller than 1 K. The films prepared at ambient pressure yielded critical current densities up to 370 000 A cm−2 at 77 K in the self-field.


PACS

74.72.Jt Other cuprates, including Tl and Hg-based cuprates

74.25.Dw Superconductivity phase diagrams

74.78.Bz High-Tc films

74.62.-c Transition temperature variations

68.55.-a Thin film structure and morphology

74.25.Sv Critical currents

Subjects

Superconductivity

Surfaces, interfaces and thin films

Dates

Issue 8 (August 2003)

Received 19 February 2003, in final form 23 May 2003

Published 22 July 2003



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