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Anisotropic grain morphology, crystallographic texture and their implications for flux pinning mechanisms in MgB2 pellets, filaments and thin films

Xueyan Song1,2, S E Babcock1,2, C B Eom1,2, D C Larbalestier1,2, K A Regan3, R J Cava3, S L Bud'Ko4, P C Canfield4 and D K Finnemore4

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Grain morphology and crystallographic texture were investigated by electron microscopy in four different polycrystalline forms of superconducting MgB2. The materials included a hot-pressed sintered MgB2 pellet, a pellet reacted in situ from Mg and B, an in situ reacted MgB2 filament and a pulsed-laser-deposited thin film grown on a single crystalline [111] oriented SrTiO3 substrate. Thick plate-shaped grains with an aspect ratio of ~3 and large faces parallel to (0001) planes dominated the microstructure in all four types of sample. The intermediate-sized plate-shaped grains (0.1 μm × 0.3 μm on average) in the electromagnetically most homogeneous parts of the hot-pressed pellets were strongly facetted, but not textured. Large (3–5 μm) plate-shaped grains were seen in the pellet reacted directly from stoichiometric Mg and B. A tendency for parallel alignment of the [0001] axes of the considerably larger grains (~0.25 μm × 1 μm) in the filament was observed near its W core, but degradation of this texture away from the core was apparent. The very small grains (~10 nm) of the thin film possessed a well-defined fibre texture with [0001] parallel to the film normal and no preferred orientation in the plane of the film. Electrical resistivity of the finest grain samples was some 103 times higher than the largest grain sample and their critical current density about one order of magnitude higher. We conclude that, in contrast to the cuprate-based high-Tc superconductors, grain boundaries do not limit the critical current density of polycrystalline MgB2 and indeed act as flux-pinning centres, which enhance the critical current density.


PACS

74.81.Bd Granular, melt-textured, amorphous and composite superconductors

74.78.Bz High-Tc films

74.25.Sv Critical currents

74.25.Fy Transport properties (electric and thermal conductivity, thermoelectric effects, etc.)

81.20.Ev Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation

Subjects

Superconductivity

Condensed matter: structural, mechanical & thermal

Dates

Issue 4 (April 2002)

Received 24 August 2001, in final form 7 December 2001

Published 20 February 2002



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