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Shear-thinning liquid films: macroscopic and asymptotic behaviour by quasi-self-similar solutions

L Ansini and L Giacomelli

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Recommended by K Ohkitani

We consider the spreading of a thin droplet of viscous liquid on a plane surface driven by capillarity in the complete wetting regime. In the case of constant viscosity, the no-slip condition leads to a force singularity at advancing contact lines. It is well known nowadays that the introduction of appropriate slip conditions removes this paradox and alters only logarithmically the macroscopic behaviour of solutions at intermediate timescales. Here, we investigate a different approach, which consists in keeping the no-slip condition and assuming instead a shear-thinning rheology. This relaxation leads, in lubrication approximation, to fourth order degenerate parabolic equations of quasilinear type. By analysing a class of quasi-self-similar solutions to these equations in the limit of Newtonian rheology, we obtain a scaling law in time for macroscopic quantities (such as macroscopic profile, effective contact-angle) which is only logarithmically affected by the shear-thinning parameters. As opposed to positive slippage models, the scaling law is uniform for large times as far as the macroscopic support is well defined, and thus could also describe the asymptotic behaviour of a large class of solutions for fixed shear-thinning rheology.


PACS

83.60.Rs Shear rate-dependent structure (shear thinning and shear thickening)

02.60.Lj Ordinary and partial differential equations; boundary value problems

68.15.+e Liquid thin films

68.08.Bc Wetting

MSC

35K60 Nonlinear boundary value problems for linear parabolic PDE; boundary value problems for nonlinear parabolic PDE

35K65 Parabolic partial differential equations of degenerate type

76D08 Lubrication theory

76A20 Thin fluid films

Subjects

Soft matter, liquids and polymers

Fluid dynamics

Computational physics

Surfaces, interfaces and thin films

Dates

Issue 6 (November 2002)

Received 28 February 2002, in final form 8 August 2002

Published 14 October 2002



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