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Plasma synthesis of single-crystal silicon nanoparticles for novel electronic device applications

Ameya Bapat1, Curtis Anderson1, Christopher R Perrey2, C Barry Carter2, Stephen A Campbell3 and Uwe Kortshagen1,4

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Single-crystal nanoparticles of silicon, several tens of nanometres in diameter, may be suitable as building blocks for single-nanoparticle electronic devices. Previous studies of nanoparticles produced in low-pressure plasmas have demonstrated the synthesis of nanocrystals 2–10 nm diameter but larger particles were amorphous or polycrystalline. This work reports the use of a constricted, filamentary capacitively coupled low-pressure plasma to produce single-crystal silicon nanoparticles with diameters between 20 and 80 nm. Particles are highly oriented with predominantly cubic shape. The particle size distribution is rather monodisperse. Electron microscopy studies confirm that the nanoparticles are highly oriented diamond-cubic silicon.


PACS

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

52.77.-j Plasma applications

Subjects

Plasma physics

Nanoscale science and low-D systems

Dates

Issue 12B (December 2004)

Received 2 July 2004

Published 17 November 2004



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