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Correlation between thermal conductivity and diffusion of gases and gas mixtures of monatomic gases

J M Gandhi and S C Saxena

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A correlation between the thermal conductivity and diffusion coefficients for monatomic gases is presented on the basis of Chapman-Enskog kinetic theory. It is tested for pure, binary and ternary gas systems, the deviation usually being 1 5 per cent. Finally, on the basis of this correlation, thermal conductivity values have been predicted for the Ar-He system at the temperatures 300, 500, 700, 900 and 1100 °K, and for percentages of argon of 20, 40, 60 and 80. These values are also compared with the directly measured values at 100, 316 and 520 °C. The two sets agree within the average absolute deviation of 2 6 per cent. This agreement should be regarded as good in view of the large experimental uncertainty associated with these data.


PACS

51.20.+d Viscosity, diffusion, and thermal conductivity

51.10.+y Kinetic and transport theory of gases

Subjects

Plasma physics

Dates

Issue 1 (January 1966)

Received 20 July 1965



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