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EMF measurements on liquid Na-Hg alloys and their thermodynamic properties

T Ishiguro, S Takeda and S Tamaki

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The EMF of the liquid Na-Hg system has been measured as a function of temperature and from these measurements we have obtained the thermodynamic quantities of mixing: Delta G, Delta S and Delta H. The temperature variations of Delta H were observed. The authors then estimated Delta Cp, the additional specific heat by alloying. In connection with this, the fluctuations in the long-wavelength limit Scc(0), SNN(0), SNc(0) and the partial structure factors aij(0) of Faber-Ziman type were estimated. They also estimated the local ordering parameter from these partial structure factors.


PACS

72.15.Cz Electrical and thermal conduction in amorphous and liquid metals and alloys

65.40.G- Other thermodynamical quantities

65.40.Ba Heat capacity

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 5 (May 1982)



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