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Four-body perimetric coordinates

Alexei M Frolov

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The new approach to the analysis of four-body systems and computation of various four-body integrals is proposed. The approach is based on the use of six perimetric coordinates which can be introduced for an arbitrary four-body system. The proper (i.e. non-conflicting) definition of the four-body perimetric coordinates is given for an arbitrary four-body system. It is shown that these six internal perimetric coordinates describe all possible configurations in an arbitrary four-body system and can be used to simplify computations of many four-body integrals written in the relative coordinates r12, r13, r23, r14, r24 and r34. In addition to this, a number of new, very effective procedures for variational computation of different four-body systems can now be developed.


PACS

02.30.Uu Integral transforms

45.10.Db Variational and optimization methods

02.30.Rz Integral equations

36.10.Dr Positronium

MSC

81V55 Molecular physics (See also 92E10)

35A22 Transform methods (e.g. integral transforms)

70G75 Variational methods

Subjects

Atomic and molecular physics

Mathematical physics

Computational physics

Dates

Issue 50 (15 December 2006)

Received 21 September 2006, in final form 7 November 2006

Published 30 November 2006



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