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Existence and construction of dynamical potential in nonequilibrium processes without detailed balance

L Yin1 and P Ao2

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The existence of a dynamical potential with both local and global meanings in general nonequilibrium processes has been controversial. Following an earlier heuristic argument in a letter by one of us, in the present paper we show rigorously its existence for a generic class of situations in physical and biological sciences. The local dynamical meaning of this potential function is demonstrated via a special stochastic differential equation and its global steady-state meaning via a novel and explicit form of the Fokker–Planck equation. We also give a procedure to obtain the special stochastic differential equation for any given Fokker–Planck equation. No detailed balance condition is required in our demonstration. For the first time we obtain here a formula to describe the noise-induced shift in drift force compared to the steady-state distribution, a phenomenon extensively observed in numerical studies.


PACS

89.75.Fb Structures and organization in complex systems

02.10.Ud Linear algebra

05.70.Ln Nonequilibrium and irreversible thermodynamics

05.10.Gg Stochastic analysis methods (Fokker-Planck, Langevin, etc.)

02.10.Yn Matrix theory

MSC

82C31 Stochastic methods (Fokker-Planck, Langevin, etc.) (See also 60H10)

82C10 Quantum dynamics and nonequilibrium statistical mechanics (general)

92D10 Genetics (For genetic algebras, see 17D92)

Subjects

Mathematical physics

Computational physics

Statistical physics and nonlinear systems

Dates

Issue 27 (7 July 2006)

Received 21 November 2005, in final form 27 April 2006

Published 21 June 2006



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