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Calculation of the microcanonical temperature for the classical Bose field

M J Davis1 and P B Blakie2

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The ergodic hypothesis asserts that a classical mechanical system will in time visit every available configuration in phase space. Thus, for an ergodic system, an ensemble average of a thermodynamic quantity can equally well be calculated by a time average over a sufficiently long period of dynamical evolution. In this paper, we describe in detail how to calculate the temperature and chemical potential from the dynamics of a microcanonical classical field, using the particular example of the classical modes of a Bose-condensed gas. The accurate determination of these thermodynamics quantities is essential in measuring the shift of the critical temperature of a Bose gas due to non-perturbative many-body effects.


PACS

03.75.Hh Static properties of condensates; thermodynamical, statistical and structural properties

05.20.-y Classical statistical mechanics

MSC

82B30 Statistical thermodynamics (See also 80-XX)

82B05 Classical equilibrium statistical mechanics (general)

Subjects

Quantum gases, liquids and solids

Statistical physics and nonlinear systems

Dates

Issue 48 (2 December 2005)

Received 29 August 2005, in final form 7 October 2005

Published 16 November 2005



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