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Langevin granulometry of the particle size distribution

Attila Kákay1, M W Gutowski2, L Takacs3, V Franco4 and L K Varga1

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The problem of deriving the particle size distribution directly from superparamagnetic magnetization curves is studied by three mathematical methods: (1) least-squares deviation with regularization procedure, (2) simulated annealing and (3) genetic algorithm. Software has been developed for the latest versions of all these methods and its performance compared for various models of underlying particle size distributions (Dirac δ-like, lognormal- and Gaussian-shaped). For single peak distributions all three methods give reasonable and similar results, but for bimodal distributions the genetic algorithm is the only acceptable one. The genetic algorithm is able to recover with the same precision both the lognormal and Gaussian single and double (mixed) model distributions. The sensitivity of the genetic algorithm—the most promising method—to uncertainty of measurements was also tested; correct peak position and its half width were recovered for Gaussian distributions, when the analysed data were contaminated with noise of up to 5% of MS.


PACS

75.20.-g Diamagnetism, paramagnetism, and superparamagnetism

02.60.Pn Numerical optimization

75.50.Tt Fine-particle systems; nanocrystalline materials

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

MSC

68W20 Randomized algorithms

93E24 Least squares and related methods

60G15 Gaussian processes

Subjects

Computational physics

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 23 (11 June 2004)

Received 4 December 2003, in final form 8 March 2004

Published 25 May 2004



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