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A new method for the solution of the Schrödinger equation

Paolo Amore1, Alfredo Aranda1 and Arturo De Pace2

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We present a new method for the solution of the Schrödinger equation applicable to problems of a non-perturbative nature. The method works by identifying three different scales in the problem, which then are treated independently: an asymptotic scale, which depends uniquely on the form of the potential at large distances; an intermediate scale, still characterized by an exponential decay of the wavefunction; and, finally, a short distance scale, in which the wavefunction is sizable. The notion of optimized perturbation is then used in the last two regimes. We apply the method to the quantum anharmonic oscillator and find it suitable to treat both energy eigenvalues and wavefunctions, even for strong couplings.


PACS

03.65.Ge Solutions of wave equations: bound states

02.10.Ud Linear algebra

03.65.Fd Algebraic methods

02.30.Mv Approximations and expansions

MSC

81Q05 Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other quantum-mechanical equations

15A18 Eigenvalues, singular values, and eigenvectors

41A60 Asymptotic approximations, asymptotic expansions (steepest descent, etc.) (See also 30E15)

81R05 Finite-dimensional groups and algebras motivated by physics and their representations (See also 20C35, 22E70)

Subjects

Mathematical physics

Quantum information and quantum mechanics

Dates

Issue 10 (12 March 2004)

Received 3 November 2003

Published 24 February 2004



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