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Localization of a random copolymer at an interface: an untethered self-avoiding walk model

E W James1, C E Soteros1,2 and S G Whittington1

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We consider two related n-step self-avoiding walk models of a copolymer at an interface between two bulk phases. In one case the walk is confined to start in the interface while in the other this condition is relaxed. We prove that both models have the same limiting free energy (in the n limit) and hence that their phase diagrams are identical. We also show that the limits n and certain energy parameters going to plus or minus infinity can be interchanged. These latter results are interesting from the viewpoint of numerical studies.


PACS

05.40.Fb Random walks and Levy flights

05.70.Ce Thermodynamic functions and equations of state

MSC

82B41 Random walks, random surfaces, lattice animals, etc. (See also 60G50, 82C41)

82D60 Polymers

Subjects

Statistical physics and nonlinear systems

Dates

Issue 44 (7 November 2003)

Received 30 May 2003

Published 22 October 2003



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