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Large amplitude femtosecond electron dynamics in metal clusters

J Daligault1 and C Guet2

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We present a theoretical model that allows us to study linear and non-linear aspects of the femtosecond electron dynamics in metal clusters. The theoretical approach consists in the classical limit of the time-dependent Kohn–Sham equations. The electrons are described by a phase-space distribution function which satisfies a Vlasov-like equation while the ions are treated classically. This allows simulations for clusters containing several hundreds of atoms and extending up to several hundreds of femtoseconds during which the description conserves the fermionic character of the electron distribution. This semi-quantal approach compares very well with the purely quantal treatment. As an application of this approach, we show the prominent role of the electron dynamics during and after the interaction with an intense femtosecond laser pulse.


PACS

36.40.Gk Plasma and collective effects in clusters

52.25.Fi Transport properties

MSC

35Q40 Equations from quantum mechanics

81S30 Phase space methods including Wigner distributions, etc.

81V45 Atomic physics

Subjects

Atomic and molecular physics

Plasma physics

Dates

Issue 22 (6 June 2003)

Received 18 October 2002, in final form 20 February 2003

Published 22 May 2003



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