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The geometrical structure of 2D bond-orientational order

Mark Bowick and Alex Travesset

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We study the formulation of bond-orientational order in an arbitrary two-dimensional geometry. We find that bond-orientational order is properly formulated within the framework of differential geometry with torsion. The torsion reflects the intrinsic frustration for two-dimensional crystals with arbitrary geometry. Within a Debye-Huckel approximation, torsion may be identified as the density of dislocations. Changes in the geometry of the system cause a reorganization of the torsion density that preserves bond-orientational order. As a byproduct, we are able to derive several identities involving the topology, defect density and geometric invariants such as Gaussian curvature. The formalism is used to derive the general free energy for a 2D sample of arbitrary geometry, in both the crystalline and hexatic phases. Applications to conical and spherical geometries are briefly addressed.


PACS

61.50.Ah Theory of crystal structure, crystal symmetry; calculations and modeling

61.50.Lt Crystal binding; cohesive energy

02.40.Hw Classical differential geometry

61.72.Lk Linear defects: dislocations, disclinations

61.50.Ks Crystallographic aspects of phase transformations; pressure effects

MSC

53Axx Classical differential geometry

82D25 Crystals (For crystallographic group theory, see 20H15)

74N05 Crystals

74E15 Crystalline structure

Subjects

Mathematical physics

Condensed matter: structural, mechanical & thermal

Dates

Issue 8 (2 March 2001)

Received 26 May 2000, in final form 14 November 2000



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