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Particle coagulation and the memory of initial conditions

Alexandria B Boehm-+, Cris Poor++ and Stanley B Grant-+

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Particle coagulation is mathematically described by an infinite set of coupled nonlinear differential equations. A solution to these equations is derived for the case in which all particle clusters possess the same reactivity (i.e. a constant kernel) and where the initial conditions are bimodal, consisting of monomers and any sized J-mers. Properties of the solution are explored and it is shown that the scaling theory developed by Swift and Friedlander (1964 J. Colloid. Sci. 19 621) and extended by van Dongen and Ernst (1984 54 1396) applies to all cluster sizes only in the limit , as reported previously by Kreer and Penrose (1994 J. Stat. Phys. 75 389). At finite times we find distinctly different scaling properties for the small and large ends of the size spectrum. Furthermore, at all times the shape of the small end of the size spectrum retains a memory of the initial conditions. These results may apply to other modes of coagulation so long as interactions between small clusters, and between small and large clusters, are as weak as the constant kernel employed here.


PACS

02.30.Hq Ordinary differential equations

89.75.Da Systems obeying scaling laws

82.70.Dd Colloids

MSC

91C15 One- and multidimensional scaling

34A34 Nonlinear equations and systems, general

91E40 Memory and learning (See also 68T05)

Subjects

Soft matter, liquids and polymers

Mathematical physics

Statistical physics and nonlinear systems

Chemical physics and physical chemistry

Dates

Issue 46 (20 November 1998)

Received 14 July 1998



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