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New lattice model for interacting, avoiding polymers with controlled length distribution

K F Freed

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A new lattice spin model for many self-avoiding polymers is introduced in which the chain length distribution is fully controllable with a single generating ('magnetic') field. The model utilises spins with additional internal symmetry degrees of freedom to impose a causal connectivity of the polymer bonds on the lattice. Use of the method of random fields then produces an equivalent n to 0 limit field theory. The Flory-Huggins theory for a polymer solution emerges simply from this field theory in the mean field approximation. Polymer-polymer interactions between polymer segments on nearest-neighbour lattice are introduced into the field theory, and the low polymer volume fraction limit of the theory reduces to the Edwards type field theory for dilute through semidilute polymer solutions. A sketch is provided towards the treatment of branched polymers with fully controllable chain and branch length distributions and branching probabilities as well as a kinetic polymerisation system governed by specified propagation and termination probabilities.


PACS

61.25.H- Macromolecular and polymers solutions; polymer melts

MSC

82B41 Random walks, random surfaces, lattice animals, etc. (See also 60G50, 82C41)

82B80 Numerical methods (Monte Carlo, series resummation, etc.) (See also 65-XX, 81T80)

82B20 Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs

82D60 Polymers

Subjects

Soft matter, liquids and polymers

Dates

Issue 5 (1 April 1985)



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