K F Freed 1985 J. Phys. A: Math. Gen. 18 871 doi:10.1088/0305-4470/18/5/019
K F Freed
Show affiliationsA new lattice spin model for many self-avoiding polymers is introduced in which the chain length distribution is fully controllable with a single generating ('magnetic') field. The model utilises spins with additional internal symmetry degrees of freedom to impose a causal connectivity of the polymer bonds on the lattice. Use of the method of random fields then produces an equivalent n to 0 limit field theory. The Flory-Huggins theory for a polymer solution emerges simply from this field theory in the mean field approximation. Polymer-polymer interactions between polymer segments on nearest-neighbour lattice are introduced into the field theory, and the low polymer volume fraction limit of the theory reduces to the Edwards type field theory for dilute through semidilute polymer solutions. A sketch is provided towards the treatment of branched polymers with fully controllable chain and branch length distributions and branching probabilities as well as a kinetic polymerisation system governed by specified propagation and termination probabilities.
61.25.H- Macromolecular and polymers solutions; polymer melts
82B41 Random walks, random surfaces, lattice animals, etc. (See also 60G50, 82C41)
82B80 Numerical methods (Monte Carlo, series resummation, etc.) (See also 65-XX, 81T80)
82B20 Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs
Issue 5 (1 April 1985)
K F Freed 1985 J. Phys. A: Math. Gen. 18 871
H U Astrom and G Benediktsson 1989 J. Phys.: Condens. Matter 1 4381
Lisa R Karam 2007 Metrologia 44 S1
T Iitaka et al 2006 J. Phys.: Conf. Ser. 29 58
Tzu-Jen Kao et al 2006 Physiol. Meas. 27 S1
A S Shumovsky and Tran Ouang 1989 J. Phys. B: At. Mol. Opt. Phys. 22 131
Gregory Ryskin 2009 New J. Phys. 11 063015
N Venkatachalam et al 2009 J. Phys.: Conf. Ser. 191 012002
S Serventi et al 2003 Supercond. Sci. Technol. 16 152
Andreas Rüdinger and Frédéric Piéchon 1997 J. Phys. A: Math. Gen. 30 117