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Thermoelectric performance of weakly coupled granular materials

A. Glatz1 and I. S. Beloborodov2

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We study thermoelectric properties of inhomogeneous nanogranular materials for weak tunneling conductance between the grains, gt<1. We calculate the thermopower and figure of merit taking into account the shift of the chemical potential and the asymmetry of the density of states in the vicinity of the Fermi surface. We show that the weak coupling between the grains leads to a high thermopower and low thermal conductivity resulting in relatively high values of the figure of merit on the order of one. We estimate the temperature at which the figure of merit has its maximum value for two- and three-dimensional samples. Our results are applicable for many emerging materials, including artificially self-assembled nanoparticle arrays.


PACS

72.15.Jf Thermoelectric and thermomagnetic effects

73.63.-b Electronic transport in nanoscale materials and structures

73.23.Hk Coulomb blockade; single-electron tunneling

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 5 (September 2009)

Received 7 July 2009, accepted for publication 26 August 2009

Published 24 September 2009



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