A. Bussmann-Holder and A. R. Bishop 2006 Europhys. Lett. 76 945 doi:10.1209/epl/i2006-10369-0
A. Bussmann-Holder1 and A. R. Bishop2
Show affiliationsStrontium titanate is an incipient ferroelectric where the freezing of the soft polar mode is inhibited by quantum fluctuations (Müller K. A. and Burhard H., Phys. Rev. B, 19 (1979) 3593). Exchanging 16O by its isotope 18O induces ferroelectricity at Tc = 25 K (Itoh M., Wang R., Inaguma Y., Yamaguchi T., Shan Y. J. and Nakamura T., Phys. Rev. Lett., 82 (1999) 3540). This finding is unexpected and its origin remains unclear since seemingly contradictory data have been obtained. Here we suggest that SrTi18O3 (STO18) exhibits self-induced intrinsic inhomogeneity due to optic–acoustic mode coupling, whereby dynamical clusters are formed with a lower symmetry than the embedding matrix. With decreasing temperature these clusters grow in size and volume fraction and remain present in the ferroelectric state leading to an incomplete ferroelectric ground state. The remaining lattice shows soft-mode behaviour. Since the length and time scales of the coexisting components differ considerably, experiments which test these scales can reach contradictory conclusions concerning the phase transition mechanism.
77.84.-s Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials
Issue 5 (December 2006)
Received 10 July 2006, accepted for publication 16 October 2006, in final form 16 October 2006
Published 10 November 2006
A. Bussmann-Holder and A. R. Bishop 2006 Europhys. Lett. 76 945
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