G. Brotons et al 2006 Europhys. Lett. 75 992 doi:10.1209/epl/i2006-10207-5
G. Brotons1,2,3, L. Belloni2, Th. Zemb2 and T. Salditt1
Show affiliationsWe have investigated the structure, fluctuations and elasticity parameters of charged fluid membranes composed of didodecyldimethylammonium halide bilayers (DDAX) with different counterions (X = Cl− or Br−) by non-specular (diffuse) X-ray scattering. The samples have been prepared as highly aligned thick stacks on silicon support and have been swollen at controlled osmotic pressures. From line-shape analysis of the diffuse scattering, we can determine the fluctuation amplitudes of the membranes in the Łα phase and the characteristic correlation lengths. According to the Caillé model, the measured structural parameters have been expressed in terms of the exponent η and smectic penetration length λ, from which the smectic compression modulus B (J/m3) and the bending modulus K (J/m) have been determined, as a function of the swelling state. We show that the results are in quantitative agreement with the mean-field electrostatic Poisson-Boltzmann calculations, controlled by the bilayers surface charge density (surfactant head groups with free or condensed counterions).
Issue 6 (September 2006)
Received 14 April 2006, accepted for publication 26 July 2006, in final form 26 July 2006
Published 23 August 2006
G. Brotons et al 2006 Europhys. Lett. 75 992
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Yurii V Dumin 2009 New J. Phys. 11 103032
Andrew DeBenedictis 1999 Class. Quantum Grav. 16 1955
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C Foias et al 2002 Nonlinearity 15 1881
Yoshitaka Fujita et al 2009 Metrologia 46 237
Claire Turner et al 2006 Physiol. Meas. 27 637
Theocharis A Apostolatos et al 2009 J. Phys.: Conf. Ser. 189 012002