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Optical evidence for a magnetically driven structural transition in the spin web Cu3TeO6

G. Caimi1, L. Degiorgi1, H. Berger2 and L. Forró2

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Cu3TeO6 is a modest frustrated S = 1/2 spin system, which undergoes an antiferromagnetic transition at TN ~ 63 K. The antiferromagnetic spin alignment in Cu3TeO6 below TN is supposed to induce a magneto-elastic strain of the lattice. The complete absorption spectrum of Cu3TeO6 is obtained through Kramers-Kronig transformation of the optical reflectivity, measured from the far-infrared up to the ultraviolet spectral range as a function of temperature (T). Below T* ~ 50 K, we find a new mode at 208 cm−1. The spectral weight associated to this additional mode increases as propto (T* − T)1/2 with decreasing T below T*. The implication of the optical findings will be discussed in relation to the magnetic phase transition at TN.


PACS

78.20.-e Optical properties of bulk materials and thin films

75.30.Gw Magnetic anisotropy

75.50.Ee Antiferromagnetics

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 3 (August 2006)

Received 30 November 2005, accepted for publication 9 June 2006, in final form 9 June 2006

Published 30 June 2006



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