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Equilibrium onions?

L. Ramos1, D. Roux2, P. D. Olmsted3 and M. E. Cates4

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We demonstrate the possibility of a stable equilibrium multi-lamellar ("onion") phase in pure lamellar systems (no excess solvent) due to a sufficiently negative Gaussian curvature modulus. The onion phase is stabilized by non-linear elastic moduli coupled to a polydisperse size distribution (Apollonian packing) to allow space-filling without appreciable elastic distortion. This model is compared to experiments on copolymer-decorated lamellar surfactant systems, with reasonable qualitative agreement.


PACS

82.70.Uv Surfactants, micellar solutions, vesicles, lamellae, amphiphilic systems, (hydrophilic and hydrophobic interactions)

68.18.Jk Phase transitions in liquid thin films

61.30.St Lyotropic phases

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 6 (June 2004)

Received 30 July 2003, accepted for publication 15 April 2004, in final form 15 April 2004



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