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Observation of a sample-dependent 37 K anomaly on the lattice parameters of strontium titanate

L. Arzel1,2, B. Hehlen1, F. Dénoyer3, R. Currat2, K.-D. Liss4 and E. Courtens1

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The lattice parameters of tetragonal strontium titanate are determined to about 1 part in 106 with penetrating X-rays. While no peculiarity is detected in a bulk sample, a distinct anomaly at 37 K is observed in an optically polished thin platelet derived from the same single crystal. This suggests that the anomaly is related to a high density of dislocations. A possible mechanism is that dislocations stabilize transverse antiphase boundaries which undergo a ferroelectric transition near 37 K. If so, this transition stresses the boundaries which then strain the bulk leading to the observed anomaly.


PACS

77.84.Dy Niobates, titanates, tantalates, PZT ceramics, etc.

61.10.-i X-ray diffraction and scattering

61.50.Ks Crystallographic aspects of phase transformations; pressure effects

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 5 (March 2003)

Received 5 August 2002, accepted for publication 16 December 2002, in final form 16 December 2002



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