Effects of Strong Rapidly Varying Flows on Fluctuations in Dilute Polymer Solutions

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Published under licence by IOP Publishing Ltd
, , Citation M. J. Hsia and B. O'Shaughnessy 1993 EPL 21 805 DOI 10.1209/0295-5075/21/8/002

0295-5075/21/8/805

Abstract

The behavior of dilute polymer solutions in strong periodic flows is studied. On time scales much greater than the flow period fluctuations in centre-of-gravity position are governed by an anisotropic and enhanced diffusivity matrix. We demonstrate that the size and density of a diffusing cloud grows and decays, respectively, more rapidly than without flow. At high frequencies the polymer chain size and monomer diffusivity are enhanced by the same "factor" as the centre-of-gravity in a Rouse dynamics treatment. Density fluctuations are anisotropic and on the average reduced by flow. All effects are non-linear in the strain amplitude of the flow.

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10.1209/0295-5075/21/8/002