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Enhancement of electroluminescence in p–i–n structures with nano-crystalline Si/SiO2 multilayers

D Y Chen1, D Y Wei1, J Xu1, P G Han1, X Wang1, Z Y Ma1, K J Chen1, W H Shi2 and Q M Wang2

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Nano-crystalline Si/SiO2 multilayers were prepared by alternately changing the ultra-thin amorphous Si film deposition and the in situ plasma oxidation process followed by the post-annealing treatments. Well-defined periodic structures can be achieved with 2.5 nm thick SiO2 sublayers. It is shown that the size of formed nano-crystalline Si is about 3 nm. Room temperature electroluminescence can be observed and the spectrum contains two luminescence bands located at 650 nm and 520 nm. In order to improve the hole injection probability, p–i–n structures containing a nanocrystalline Si/SiO2 luminescent layer were designed and fabricated on different p-type substrates. It is found that the turn-on voltage of p–i–n structures is obviously reduced and the luminescence intensity increases by 50 times. It is demonstrated that the use of a heavy-doped p-type substrate can increase the luminescence intensity more efficiently compared with the light-doped p-type substrate due to the enhanced hole injection.


PACS

78.60.Fi Electroluminescence

81.40.Ef Cold working, work hardening; annealing, post-deformation annealing, quenching, tempering recovery, and crystallization

73.40.Lq Other semiconductor-to-semiconductor contacts, p-n junctions, and heterojunctions

85.30.Kk Junction diodes

68.55.-a Thin film structure and morphology

61.46.Hk Nanocrystals

Subjects

Electronics and devices

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (January 2008)

Received 25 July 2007, in final form 1 November 2007

Published 12 December 2007



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