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Optical emission from InAs/InP self-assembled quantum dots: evidence for As/P intermixing

A Lanacer1, N Shtinkov2, P Desjardins3, R A Masut3 and R Leonelli1

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We have studied the optical properties of ultrathin InAs/InP quantum wells and Stranski–Krastanov nanostructures using photoluminescence and photoluminescence excitation experiments. For InAs epilayers thinner than 2.4 monolayers, the emission spectrum consists of a single peak and the ground-state exciton energy is in good agreement with predictions based on the tight-binding method for ultrathin quantum wells. Beyond this thickness, the photoluminescence spectra evolve to a multimodal emission indicative of the presence of families of quantum dots with small heights. The emission of these quantum dots is blue-shifted significantly (~100 meV) from the predicted values. The discrepancy is explained by As/P intermixing that occurs during quantum dot formation.


PACS

78.67.Hc Quantum dots

78.55.Cr III-V semiconductors

73.21.La Quantum dots

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 12 (December 2007)

Received 10 July 2007, in final form 11 July 2007

Published 1 November 2007



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