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DNA-decorated carbon nanotubes for chemical sensing

A T Charlie Johnson1, Cristian Staii1,5, Michelle Chen2, Sam Khamis1, Robert Johnson1, M L Klein3 and A Gelperin4

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We demonstrate a versatile class of nanoscale chemical sensors based on single-stranded DNA (ssDNA) for chemical recognition and single-walled carbon nanotube field effect transistors (SWNT FETs) for electronic read-out. SWNT FETs with a nanoscale coating of ssDNA respond to vapours that cause no detectable conductivity change in bare devices. The gases tested are methanol, trimethylamine, propionic acid, dimethylmethylphosphonate and dinitrotoluene. Sensor responses differ in sign and magnitude for different gases and can be tuned by choice of the ssDNA base sequence. Sensors respond and recover rapidly (seconds), and the sensor surface is self-regenerating. Preliminary results of all-atom molecular dynamics simulations are consistent with experiment.


PACS

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

87.14.G- Nucleic acids

87.80.-y Biophysical techniques (research methods)

85.35.Kt Nanotube devices

87.15.Cc Folding: thermodynamics, statistical mechanics, models, and pathways

Subjects

Electronics and devices

Instrumentation and measurement

Medical physics

Biological physics

Nanoscale science and low-D systems

Dates

Issue 11 (November 2006)

Received 10 July 2006, in final form 15 September 2006

Published 18 October 2006



  1. DNA-decorated carbon nanotubes for chemical sensing

    A T Charlie Johnson et al 2006 Semicond. Sci. Technol. 21 S17

  2. Current status of AlInN layers lattice-matched to GaN for photonics and electronics

    R Butté et al 2007 J. Phys. D: Appl. Phys. 40 6328

  3. Selective inactivation of micro-organisms with near-infrared femtosecond laser pulses

    K T Tsen et al 2007 J. Phys.: Condens. Matter 19 472201

  4. Control and placement of molecules via self-assembly

    P A Lewis et al 2001 Nanotechnology 12 231

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