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1/f noise and dye-sensitized solar cells

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P V V Jayaweera1,2, P K D D P Pitigala2, A G U Perera1,2 and K Tennakone1,2

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LETTER TO THE EDITOR

The adsorbed molecular species, such as H2O and I2, that produce electron acceptor states on the TiO2 surface are found to generate 1/f noise in the electric current through nanocrystalline films of TiO2. It is suggested that the trapping and detrapping of electrons at the surface states is the cause of this noise. When the TiO2 film surface is coated with dyes, the passivation of the active surface sites suppresses 1/f noise. Implications of 1/f noise on the functioning of the dye-sensitized solar cell, notably the effect of adsorbed iodine in inducing recombinations, are discussed.


PACS

72.70.+m Noise processes and phenomena

73.20.At Surface states, band structure, electron density of states

81.65.Rv Passivation

73.20.Hb Impurity and defect levels; energy states of adsorbed species

84.60.Jt Photoelectric conversion: solar cells and arrays

Subjects

Electronics and devices

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 8 (August 2005)

Received 18 May 2005, in final form 28 June 2005

Published 18 July 2005



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