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Solar cell with extremely thin absorber on highly structured substrate

K Ernst, A Belaidi and R Könenkamp1

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We report the optical, structural and photovoltaic properties of an extremely-thin-absorber (eta) solar cell on highly porous TiO2 substrates. Nano-crystalline absorber layers with a local thickness of only 150 nm have been prepared. This small absorber thickness allows good carrier collection even for absorber material with poor transport properties. The morphology of the highly structured TiO2 substrate produces strong internal light scattering, resulting in an enhancement of the optical path length by a factor 5. With 150 nm thick CdTe absorber layers, the eta solar cells produce an open-circuit voltage of 0.67 V and a short-circuit current of 8.9 mA cm−2 for 100 mW cm−2 illumination. Alloying the CdTe with Hg improves the short-circuit current to 15 mA cm−2.


PACS

84.60.Jt Photoelectric conversion: solar cells and arrays

78.35.+c Brillouin and Rayleigh scattering; other light scattering

68.47.Gh Oxide surfaces

42.25.Fx Diffraction and scattering

Subjects

Condensed matter: electrical, magnetic and optical

Electronics and devices

Surfaces, interfaces and thin films

Optics, quantum optics and lasers

Dates

Issue 6 (June 2003)

Received 19 February 2003, in final form 18 March 2003

Published 14 April 2003



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