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Nature of some electron traps in GaP

A V Skazochkin, Yu K Krutogolov and Yu I Kunakin

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The effect on point defects of annealing in a phosphorus vapour is studied on GaP:N layers grown by vapour phase epitaxy. When the pressure P of the phosphorus (P4) vapour is varied, the concentration of the deep centre, thermally activated with an activation energy of 0.24+or-0.01 eV given by DLTS, exhibits P-1/4 behaviour, which suggests that this centre is related to phosphorus vacancies. Based on the experimental data obtained, the known models of the nitrogen-related deep centre are analysed and the formation of such a centre is considered in the case when the background Si is the dominant donor impurity. The centre is shown to differ from defects formed with the participation of group VI elements, and a model of the centre is proposed.


PACS

68.55.Ln Defects and impurities: doping, implantation, distribution, concentration, etc.

81.15.Kk Vapor phase epitaxy; growth from vapor phase

71.55.Eq III-V semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Dates

Issue 5 (May 1995)



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