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Structural Feature and Solute Trapping of Rapidly Grown Ni3Sn Intermetallic Compound

Qin Hai-Yan, Wang Wei-Li and Wei Bing-Bo

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CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY

The rapid dendritic growth of primary Ni3Sn phase in undercooled Ni-30.9%Sn-5%Ge alloy is investigated by using the glass fluxing technique. The dendritic growth velocity of Ni3Sn compound is measured as a function of undercooling, and a velocity of 2.47 m/s is achieved at the maximum undercooling of 251 K (0.17TL). The addition of the Ge element reduces its growth velocity as compared with the binary Ni75Sn25 alloy. During rapid solidification, the Ni3Sn compound behaves like a normal solid solution and it displays a morphological transition of "coarse dendrite–equiaxed grain–vermicular structure" with the increase of undercooling. Significant solute trapping of Ge atoms occurs in the whole undercooling range.


PACS

68.70.+w Whiskers and dendrites (growth, structure, and nonelectronic properties)

64.70.D- Solid–liquid transitions

61.66.Dk Alloys

81.30.Fb Solidification

Subjects

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 21 August 2009



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